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Chem 322

Chem 322-011. Organic Chemistry - 2
Spring 2014

Instructor: Mary Watson (mpwatson[at]udel.edu)

Office Hours: Tues, 3:30–4:30pm, 220 BRL || Thurs, 10:30–11:30am, 220 BRL

Lectures: TuTh, 2–3:15pm, 101 BRL

Exams:

Midterm 1: Sat, March 8, 10am–12pm, 100 KRB

Midterm 2: Sat, April 12, 10am–12pm, 100 KRB

Midterm 3: Sat, May 3, 10am–12pm, 100 KRB

Final: Wed, May 28, 7–10pm, 140 Smith

UDCapture: http://udcapture.udel.edu/2014s/chem322-011/

Link to Lab Website: Canvas Website

Link to Dr. Heitbrink’s Chem 322 Sakai Site: https://sakai.udel.edu/portal/site/4978a0ed-09f8-4512-a876-ea63e1ad76aa


Syllabus.pdf


Music Video Throwdown.pdf


Review Sessions/Office Hours to Prepare for the Final Exam

Tues, 5/20, 12:30–1:30 (208 Gore, Jixin)

Tues, 5/20, 3:30–4:30 (220 BRL, Mary)

Wed, 5/21, 12:00–2:00 (101 BRL, Bruce)

Thurs, 5/22, 10:30–11:30 (220 BRL, Mary)

Tues, 5/27, 12:30–1:30 (205 BRL, Songnan)

Tues, 5/27, 3:30–5:00 (319 WHL, Mary & Kelsey)


Discussion Sections (very highly recommended!)

Please note: As of 3/21/14, the Discussion Section on Tuesdays from 8–9pm has been cancelled due to low attendance.













TA Office Hours

Please note: As of 3/21/14, the TA Office Hours on Thursdays and Fridays have been cancelled due to low attendance.








Lecture Notes & Handouts (will be posted shortly after lecture)

Aromaticity (Chapter 13)

Recommended Practice Problems: 13.28–13.52, 13.56–13.60

Review_Lecture1.pdf

Bilirubin.pdf

Aromaticity_Lecture1.pdf

Aromaticity_Lecture2.pdf

Aromaticity_Lecture3.pdf

Aromaticity_Lecture4.pdf


Substitution Reactions of Aromatic Compounds (Chapter 14)

Recommended Practice Problems: 14.45–14.52, 14.54–14.55, 14.57–14.65, 14.71, 14.75

AromaticSubstitution_Lecture4.pdf

AromaticSubstitution_Lecture5.pdf

AromaticSubstitution_Lecture6.pdf

Handout on Substituent Effects: EASgroups.pdf

AromaticSubstitution_Lecture7.pdf

HeckReaction_Lecture7.pdf


Spectroscopy (Chapter 15)

Recommended Practice Problems: 15.32–15.62, 15.64–15.89

Spectroscopy_Lecture8.pdf

Spectroscopy_Lecture9a.pdf

Spectroscopy_Lecture9b.pdf

Spectroscopy_Lecture9_Handout.pdf

Spectroscopy_Lecture10_Handout_1HNMR.pdf

Spectroscopy_Lecture11.pdf

Spectroscopy_Lecture12.pdf

Spectroscopy_Lecture12_Handout_NMR.pdf

For extra practice, see:

WebSpectra

Unknowns Spectra.pdf


Carbonyl Chemistry (Chapter 16)

Recommended Practice Problems: 16.31–16.52, 16.55-16.60, 16.62-16.65, 16.67, 16.69

CarbonylChemistry_Lecture12.pdf

CarbonylChemistry_Lecture13.pdf

CarbonylChemistry_Lecture14.pdf

CarbonylChemistry_Lecture15.pdf


Carboxylic Acids and Derivatives (Chapters 17 and 18)

Recommended Practice Problems: 17.25–17.35, 17.36a–c, 17.37–17.42, 17.44–17.46, 17.48, 17.49b–d. 17.51, 18.33–18.39, 18.42–18.45, 18.48–18.49, 18.50 (skip b), 18.52, 18.60 (through intermediate C), 18.61

CarboxylicAcids_Lecture15.pdf

CarboxylicAcids_Lecture16.pdf

CarboxylicAcids_Lecture17.pdf

CarboxylicAcids_Lecture18.pdf


Enols and Enolates (Chapter 19)

Recommended Practice Problems: 19.46–63, 19.67, 19.68a, 19.70–79, 19.81, 19.83–84, 19.86–87, 19.90, 19.95

Enolates_Lecture19.pdf

Enolates_Lecture20.pdf

Enolates_Lecture21.pdf


Carbohydrates (Chapter 22)

Recommended Practice Problems: 22.26–27, 22.31–33, 22.39, 22.41–45, 22.49

Carbohydrates_Lecture21.pdf

Carbohydrates_Lecture22.pdf

Carbohydrates_Lecture23.pdf


Amino Acids, Peptides & Proteins (Chapter 23)

Recommended Practice Problems: 23.26–30, 23.32, 23.37, 23.40–43

AminoAcids_Lecture23.pdf

AminoAcids_Lecture24.pdf

AminoAcid_Handout.pdf


Discussion Section Worksheets

Discussion Section 1 Aromaticity.pdf

Discussion Section 2 Aromaticity.pdf

Discussion Section 3 Aromatic Substitution.pdf

Discussion Section 4: Review of Midterm 1 (Please see test and answer key below.)

Discussion Section 5 Spectroscopy.pdf

Discussion Section 6 Spectroscopy.pdf

Discussion Section 7 Carbonyls.pdf

Discussion Section 8 Carbonyls.pdf

Section 9 Arrow Pushing Practice.pdf

Discussion Section 10 Carboxylic Acids.pdf

Discussion Section 11 Enolates.pdf

Discussion Section 12 Sugars.pdf


Exams

Midterm 1

CHEM322_Midterm1_2014.pdf

CHEM322_Midterm1_2014_AnswerKey.pdf


Midterm 2

Midterm_2_Answer_Key.pdf

Midterm 2 MakeUp.pdf

Midterm 2 MakeUp Answer Key.pdf


Midterm 3

CHEM322_Midterm3_2014.pdf

CHEM322_Midterm3_AnswerKey_2014.pdf

Midterm 3 MakeUp.pdf

Midterm 3 MakeUp Answer Key.pdf


Old Exams

CHEM322_Midterm1_2011.pdf (Please note that this exam covered Chapters 12–14.)

CHEM322_Midterm1_AnswerKey.pdf

CHEM322_Midterm2_2011.pdf

Chem322_Midterm2_2011_AnswerKey.pdf

Chem322_Midterm3_2011.pdf

Chem322_Midterm3_2011_AnswerKey.pdf

Chem322_S11_Final.pdf

Chem322_S11_Final_AnswerKey.pdf