Assignments in Physical Chemistry, CHEM 443
University of Delaware
Fall, 2012

PERIOD

ASSIGNMENT

Week 1
beginning 8/27

1: 1-5; 7: 1-5
Introduction to Course; Temperature Scales; Ideal Gas Thermometer; Properties of Matter; Equations of State; Math Review

Appendix A.1 – A.4

1. 1, 2, 4, 5, 6, 10, 11, 12, 14, 18, 21

Week 2
beginning 9/3
Quiz 1

2: 1-10

First Law of Thermodynamics; Work Interactions; Heat; Heat Capacity; State Functions; Path Functions; Reversibility; Internal Energy

2. 1,2, 7, 9, 12, 20

Week 3
beginning 9/10
Quiz 2

3: 1-8

_
First Law; Enthalpy; Joule Free Expansion; Joule-Thomson Experiment; Temperature and Volume Dependence of Internal Energy; Temperature and Pressure Dependence of Enthalpy;

3. 2, 3, 5, 6, 8, 9, 12, 15, 31

Week 4
beginning 9/17
Quiz 3

4: 1-5

Thermodynamic Calculations using First Law; Reversible Expansion/Compression of Ideal Gas; Adiabatic Processes; Thermochemistry; Hess' Law; Heat of Formation; Heat of Reactions; Temperature Dependence of Heats of Reaction; Calorimetry

4.  2, 3, 4, 5, 6, 11, 12, 20

Week 5
beginning 9/24

Quiz 4

7: 1-4;_

Real / Non-Ideal Fluids; Equations of State for Real Fluids; Compressibility Factor; Virial Equations of State; Cubic Equations of State; Relevance of Atomic Properties in Real Fluid Equations of State; Connection between Real Fluid EOS Parameters and Critical Constants thermochemistry

7.  1, 2, 3, 4, 6, 11, 12, 13, 15, 17, 18, 19 

Midterm Exam 1, Friday, October 5, 10:10 - 11 am,  109 Sharp Lab

PERIOD

ASSIGNMENT

Week 6
beginning 10/1

Midterm Exam 1

5: 1-3
Entropy; Second Law; Heat Engines; Efficiency; Carnot Cycle / Engine; Reversible Engines; Thermodynamic Cycles

5. 2, 3, 4, 5, 9, 10, 17

Week 7
beginning 10/8
Quiz 5

5: 4-14

Entropy Calculations; Microscopic View of Entropy; Third Law; Standard States

5. 1, 12, 17, 23, 26, 28, 34, 35, 40, 43, 44

Week 8
beginning 10/15

Quiz 6

6: 1-15
Gibbs and Helmholtz energies; Gibbs energy of mixing; Equilibrium Criteria; Criteria for Spontaneous Processes; Chemical Potential; Chemical Reaction Equilibria; Equilibrium Constant

6. 1, 3, 5, 8, 10, 17, 22

Week 9
beginning 10/22

Quiz 7

8: 1-9

Clapeyron equation; Clausius-Clapeyron equation; chemical potential and phase transitions

8. 3, 5, 7, 19, 24

Week 10
beginning 10/29

Quiz 8

8: 1-9
Phase Diagrams; Vapor Liquid Equilibria; Chemical Equilibrium

8. 3, 5, 7 , 19, 24

PERIOD

ASSIGNMENT

Week 11
beginning 11/5

Quiz 9

9: 1-13
Solutions; Raoult's law; Henry's law; colligative properties

9. 1, 6, 13, 19, 26

 

Midterm Exam 2, Friday, November 16, 10:10 - 11 am,  109 Sharp Lab

 

Week 12
beginning 11/12
Midterm Exam 2

10: 1-5
Ionic solutions

10. 1, 3, 7

 

Thanksgiving Recess, November 20- 25 No classes, Classes Resume November 26, 2012

 

Week 13
beginning 11/19

 

10: 1-5

Electrochemistry

10. 10, 20, 27

 

PERIOD

ASSIGNMENT

Week 14
beginning 11/26
Quiz 10

11: 1-16

Thermodynamics of electrical cells

11. 3, 5, 12, 14, 16

Week 15
beginning 12/3

Semester review

 

Last class day: December 5, 2012

Final Exam: December ??, TBA

C443 Home Page

This page was prepared and is maintained by Cecil Dybowski and Andrew Teplyakov, 1999-2008
Last revised, October 23, 2008.
URL of this document: http://www.udel.edu/pchem/C443/assign.htm